Hans-Jürgen Fachmann Knihy

InhaltsverzeichnisAcyclic Sulfur(II)-Nitrogen Compounds and Derivatives.1 Sulfur Imide and Derivatives.2 Disulfur Nitride, Nitrogen Disulfide, SNS.3 Dithionitrous Acid and Derivatives.4 Salts of the Dithionitryl Ion (1+), [S=N=S]+.5 Dinitrogen Sulfide, SNN.6 N-Thionitroso-diorganylamines and Derivatives.7 Thiohydroxylamine and Derivatives.8 Thiooximes and Derivatives.9 Thiofulminic Acid and Derivatives.10 Isohypothiocyanous Acid Ion (1?), OCNS?.11 Thionitrous Acid and Derivatives.12 Sulfur Amide Halogenides and Derivatives.13 Sulfur Amide Hydroxide Derivatives, N, N-Substituted Amino-organyloxy-sulfanes.14 S-Phosphorus-Substituted Thiohydroxylamines and Derivatives.

The present volume is the first of a series describing acyclic sulfur-nitrogen compounds with sulfur of oxidation number IV. The acyclic sw-N compounds are arranged according to the coordination number of the sulfur. Neutral compounds are described before ions and complex compounds. The preceding series „Sulfur-Nitrogen Compounds“ Parts 2, 3, and 4 covers the cyclic sw-N compounds. In this volume, the first section deals with sulfur-nitrogen compounds with 1-coordinate sulfur and begins with the sulfur nitride {thiazyl) radical, SN. This transient molecule was observed in its electronic ground state and several electronically excited states. The descrip tions of the sulfur nitride (thiazyl) ions SN+ and SW follow. The SN+ ionwas studied in the gas phase as weil as in the solid state where it forms salts. Thionitrosyl complexes containing the SN Iigand as a terminal linear unit are described at the end of the first section. The second section concerns Sulfur-nitrogen compounds with 2-coordinate sulfur and starts with the description of poly(sulfur nitride), (SNlx· The preparation, crystal structure, and metallic and superconducting properties of (SN)x, which were extensively studied, fill a ! arge part of the volume. Halogen-modified poly(sulfur nitride) such as the widely studied (SNBr )x 04 and Na-modified poly(sulfur nitride) are dealt with in the following chapters.